III OCl2 OF2 The bond angle is greater in OCl2 than in OF2 because there are some pi interactions in OCl2 involving donation from the filled p-orbitals on oxygen into the empty d-orbitals on chlorine. No pi-bonding is possible for OF2 because all orbitals (2024)

`); let searchUrl = `/search/`; history.forEach((elem) => { prevsearch.find('#prevsearch-options').append(`

${elem}

`); }); } $('#search-pretype-options').empty(); $('#search-pretype-options').append(prevsearch); let prevbooks = $(false); [ {title:"Recently Opened Textbooks", books:previous_books}, {title:"Recommended Textbooks", books:recommended_books} ].forEach((book_segment) => { if (Array.isArray(book_segment.books) && book_segment.books.length>0 && nsegments<2) { nsegments+=1; prevbooks = $(`

  • ${book_segment.title}
  • `); let searchUrl = "/books/xxx/"; book_segment.books.forEach((elem) => { prevbooks.find('#prevbooks-options'+nsegments.toString()).append(`

    ${elem.title} ${ordinal(elem.edition)} ${elem.author}

    `); }); } $('#search-pretype-options').append(prevbooks); }); } function anon_pretype() { let prebooks = null; try { prebooks = JSON.parse(localStorage.getItem('PRETYPE_BOOKS_ANON')); }catch(e) {} if ('previous_books' in prebooks && 'recommended_books' in prebooks) { previous_books = prebooks.previous_books; recommended_books = prebooks.recommended_books; if (typeof PREVBOOKS !== 'undefined' && Array.isArray(PREVBOOKS)) { new_prevbooks = PREVBOOKS; previous_books.forEach(elem => { for (let i = 0; i < new_prevbooks.length; i++) { if (elem.id == new_prevbooks[i].id) { return; } } new_prevbooks.push(elem); }); new_prevbooks = new_prevbooks.slice(0,3); previous_books = new_prevbooks; } if (typeof RECBOOKS !== 'undefined' && Array.isArray(RECBOOKS)) { new_recbooks = RECBOOKS; for (let j = 0; j < new_recbooks.length; j++) { new_recbooks[j].viewed_at = new Date(); } let insert = true; for (let i=0; i < recommended_books.length; i++){ for (let j = 0; j < new_recbooks.length; j++) { if (recommended_books[i].id == new_recbooks[j].id) { insert = false; } } if (insert){ new_recbooks.push(recommended_books[i]); } } new_recbooks.sort((a,b)=>{ adate = new Date(2000, 0, 1); bdate = new Date(2000, 0, 1); if ('viewed_at' in a) {adate = new Date(a.viewed_at);} if ('viewed_at' in b) {bdate = new Date(b.viewed_at);} // 100000000: instead of just erasing the suggestions from previous week, // we just move them to the back of the queue acurweek = ((new Date()).getDate()-adate.getDate()>7)?0:100000000; bcurweek = ((new Date()).getDate()-bdate.getDate()>7)?0:100000000; aviews = 0; bviews = 0; if ('views' in a) {aviews = acurweek+a.views;} if ('views' in b) {bviews = bcurweek+b.views;} return bviews - aviews; }); new_recbooks = new_recbooks.slice(0,3); recommended_books = new_recbooks; } localStorage.setItem('PRETYPE_BOOKS_ANON', JSON.stringify({ previous_books: previous_books, recommended_books: recommended_books })); build_popup(); } } var whiletyping_search_object = null; var whiletyping_search = { books: [], curriculum: [], topics: [] } var single_whiletyping_ajax_promise = null; var whiletyping_database_initial_burst = 0; //number of consecutive calls, after 3 we start the 1 per 5 min calls function get_whiletyping_database() { //gets the database from the server. // 1. by validating against a local database value we confirm that the framework is working and // reduce the ammount of continuous calls produced by errors to 1 per 5 minutes. return localforage.getItem('whiletyping_last_attempt').then(function(value) { if ( value==null || (new Date()) - (new Date(value)) > 1000*60*5 || (whiletyping_database_initial_burst < 3) ) { localforage.setItem('whiletyping_last_attempt', (new Date()).getTime()); // 2. Make an ajax call to the server and get the search database. let databaseUrl = `/search/whiletype_database/`; let resp = single_whiletyping_ajax_promise; if (resp === null) { whiletyping_database_initial_burst = whiletyping_database_initial_burst + 1; single_whiletyping_ajax_promise = resp = new Promise((resolve, reject) => { $.ajax({ url: databaseUrl, type: 'POST', data:{csrfmiddlewaretoken: "nGpgWvid0wI2OjHXiRKKHhDkop3Pn3RT9pAFmh9iOGVqpoIYf2IatNEkXAGCsyMP"}, success: function (data) { // 3. verify that the elements of the database exist and are arrays if ( ('books' in data) && ('curriculum' in data) && ('topics' in data) && Array.isArray(data.books) && Array.isArray(data.curriculum) && Array.isArray(data.topics)) { localforage.setItem('whiletyping_last_success', (new Date()).getTime()); localforage.setItem('whiletyping_database', data); resolve(data); } }, error: function (error) { console.log(error); resolve(null); }, complete: function (data) { single_whiletyping_ajax_promise = null; } }) }); } return resp; } return Promise.resolve(null); }).catch(function(err) { console.log(err); return Promise.resolve(null); }); } function get_whiletyping_search_object() { // gets the fuse objects that will be in charge of the search if (whiletyping_search_object){ return Promise.resolve(whiletyping_search_object); } database_promise = localforage.getItem('whiletyping_database').then(function(database) { return localforage.getItem('whiletyping_last_success').then(function(last_success) { if (database==null || (new Date()) - (new Date(last_success)) > 1000*60*60*24*30 || (new Date('2023-04-25T00:00:00')) - (new Date(last_success)) > 0) { // New database update return get_whiletyping_database().then(function(new_database) { if (new_database) { database = new_database; } return database; }); } else { return Promise.resolve(database); } }); }); return database_promise.then(function(database) { if (database) { const options = { isCaseSensitive: false, includeScore: true, shouldSort: true, // includeMatches: false, // findAllMatches: false, // minMatchCharLength: 1, // location: 0, threshold: 0.2, // distance: 100, // useExtendedSearch: false, ignoreLocation: true, // ignoreFieldNorm: false, // fieldNormWeight: 1, keys: [ "title" ] }; let curriculum_index={}; let topics_index={}; database.curriculum.forEach(c => curriculum_index[c.id]=c); database.topics.forEach(t => topics_index[t.id]=t); for (j=0; j

    Solutions
  • Textbooks
  • `); } function build_solutions() { if (Array.isArray(solution_search_result)) { const viewAllHTML = userSubscribed ? `View All` : ''; var solutions_section = $(`
  • Solutions ${viewAllHTML}
  • `); let questionUrl = "/questions/xxx/"; let askUrl = "/ask/question/xxx/"; solution_search_result.forEach((elem) => { let url = ('course' in elem)?askUrl:questionUrl; let solution_type = ('course' in elem)?'ask':'question'; let subtitle = ('course' in elem)?(elem.course??""):(elem.book ?? "")+"    "+(elem.chapter?"Chapter "+elem.chapter:""); solutions_section.find('#whiletyping-solutions').append(` ${elem.text} ${subtitle} `); }); $('#search-solution-options').empty(); if (Array.isArray(solution_search_result) && solution_search_result.length>0){ $('#search-solution-options').append(solutions_section); } MathJax.typesetPromise([document.getElementById('search-solution-options')]); } } function build_textbooks() { $('#search-pretype-options').empty(); $('#search-pretype-options').append($('#search-solution-options').html()); if (Array.isArray(textbook_search_result)) { var books_section = $(`
  • Textbooks View All
  • `); let searchUrl = "/books/xxx/"; textbook_search_result.forEach((elem) => { books_section.find('#whiletyping-books').append(` ${elem.title} ${ordinal(elem.edition)} ${elem.author} `); }); } if (Array.isArray(textbook_search_result) && textbook_search_result.length>0){ $('#search-pretype-options').append(books_section); } } function build_popup(first_time = false) { if ($('#search-text').val()=='') { build_pretype(); } else { solution_and_textbook_search(); } } var search_text_out = true; var search_popup_out = true; const is_login = false; const user_hash = null; function pretype_setup() { $('#search-text').focusin(function() { $('#search-popup').addClass('show'); resize_popup(); search_text_out = false; }); $( window ).resize(function() { resize_popup(); }); $('#search-text').focusout(() => { search_text_out = true; if (search_text_out && search_popup_out) { $('#search-popup').removeClass('show'); } }); $('#search-popup').mouseenter(() => { search_popup_out = false; }); $('#search-popup').mouseleave(() => { search_popup_out = true; if (search_text_out && search_popup_out) { $('#search-popup').removeClass('show'); } }); $('#search-text').on("keyup", delay(() => { build_popup(); }, 200)); build_popup(true); let prevbookUrl = `/search/pretype_books/`; let prebooks = null; try { prebooks = JSON.parse(localStorage.getItem('PRETYPE_BOOKS_'+(is_login?user_hash:'ANON'))); }catch(e) {} if (prebooks && 'previous_books' in prebooks && 'recommended_books' in prebooks) { if (is_login) { previous_books = prebooks.previous_books; recommended_books = prebooks.recommended_books; if (prebooks.time && new Date().getTime()-prebooks.time<1000*60*60*6) { build_popup(); return; } } else { anon_pretype(); return; } } $.ajax({ url: prevbookUrl, method: 'POST', data:{csrfmiddlewaretoken: "nGpgWvid0wI2OjHXiRKKHhDkop3Pn3RT9pAFmh9iOGVqpoIYf2IatNEkXAGCsyMP"}, success: function(response){ previous_books = response.previous_books; recommended_books = response.recommended_books; if (is_login) { localStorage.setItem('PRETYPE_BOOKS_'+user_hash, JSON.stringify({ previous_books: previous_books, recommended_books: recommended_books, time: new Date().getTime() })); } build_popup(); }, error: function(response){ console.log(response); } }); } $( document ).ready(pretype_setup); $( document ).ready(function(){ $('#search-popup').on('click', '.search-view-item', function(e) { e.preventDefault(); let autoCompleteSearchViewUrl = `/search/autocomplete_search_view/`; let objectUrl = $(this).attr('href'); let selectedId = $(this).data('objid'); let searchResults = []; $("#whiletyping-solutions").find("a").each(function() { let is_selected = selectedId === $(this).data('objid'); searchResults.push({ objectId: $(this).data('objid'), contentType: $(this).data('contenttype'), category: $(this).data('category'), selected: is_selected }); }); $("#whiletyping-books").find("a").each(function() { let is_selected = selectedId === $(this).data('objid'); searchResults.push({ objectId: $(this).data('objid'), contentType: $(this).data('contenttype'), category: $(this).data('category'), selected: is_selected }); }); $.ajax({ url: autoCompleteSearchViewUrl, method: 'POST', data:{ csrfmiddlewaretoken: "nGpgWvid0wI2OjHXiRKKHhDkop3Pn3RT9pAFmh9iOGVqpoIYf2IatNEkXAGCsyMP", query: $('#search-text').val(), searchObjects: JSON.stringify(searchResults) }, dataType: 'json', complete: function(data){ window.location.href = objectUrl; } }); }); });
    III OCl2 OF2 The bond angle is greater in OCl2 than in OF2 because there are some pi interactions in OCl2 involving donation from the filled p-orbitals on oxygen into the empty d-orbitals on chlorine. No pi-bonding is possible for OF2 because all orbitals (2024)

    FAQs

    Why does OCl2 have a larger bond angle than OF2? ›

    The bond angle is greater in OCl2 than in OF2 because there is some π interactions in OCl2 involving donation from the filled p-orbitals on oxygen into the empty d-orbitals on chlorine No π-bonding is possible for OF2 because all orbitals are filled on both atoms.

    Why the bond angle in OF2 is less than the bond angle in Cl2O? ›

    Explanation: Because oxygen in Cl₂O exhibits stronger electronegativity than chlorine, its bond angle is bigger than that of OF₂. As a result, oxygen and the shared electron pair are becoming closer to one another. Offer repulsion and an increase in angle as a result.

    Which one has greater bond angle between Cl2O and f2 and why? ›

    Answer. because in Cl2O oxygen has more electro-negativity than chlorine. Hence the shared electron pair is closer to oxygen which in turn get more closer to each other. Thus offer repulsion and increase in angle.

    What is the increasing order of bond angles in OCl2 ClO2? ›

    Answer: Explanation: OF2. OF2 < H2O < OCl2 < ClO2 is the correct increasing order of bond angle .

    What makes a bond angle larger? ›

    As more electron density remains on the central atom, electron repulsion between the bonded pairs increases and bond angles increase.

    Why is clo2 bond angle greater than Cl2O? ›

    in case of clo2 there will be less repulsion hence bond angle will be greater and in case of cl2o there will be more repulsion hence bond angle will be be lesser in comparison to clo2.

    What is the angle of OCl2? ›

    OCl2 is a sp3 hybridized structure with 2 lone pairs . So resultant shape is V-Type . We know that in sp3 structure bond angle is 109.47 but high electro-negative oxygen atom, attracts Cl-O bonded electrons toward oxygen creating repulsions . So angle is slightly increases to 110.9.

    Which has more bond angle, OBr2 or OCl2? ›

    And therefore the repulsion between bonding electrons is more in OBr2. Moreover the size of Br is bigger than Cl′s. So OBr2 has a greater bond angle than OCl2.

    What is the bond angle order of OCl2 and SCl2? ›

    Therefore, VSEPR predicts that each molecule will be bent with the bonds and lone pairs taking the shape of a tetrahedron. This predicts an angle of 109.5 deg for each moleule. The observed angles are 111 deg for OCl2 and 103 deg for SCl2.

    What is the highest bond angle in Cl2O? ›

    In Cl2O, due to non bonding electron pair repulsion (NBEPR), the bond angle is increased to 110.9o.

    What is the bond angle of Cl2O F2O? ›

    Bond angle refers to the angle between the two bonds i.e. the angle between two orbitals that contains a pair of bonding electron around the central atom in a complex molecule or an ion. This angle is usually measured in degrees, further calculated using the spectroscopic method.

    What is the bond order of clo2 Cl2O clo2? ›

    The correct bond length order of this compound is, ClO 2 + < ClO 2 < ClO 2 − < Cl 2 O .

    Why is OCl2 bond angle more than H2O? ›

    In both the compounds O is the central atom but, Cl being excessively large with lone pairs causes strong repulsion with the other Cl atom in Cl2O thereby increasing the bond angle. However H is the smallest element and the repulsion between individual H atoms is very weak, thus it has a relatively smaller bond angle.

    What is the bond angle between OCl2? ›

    OCl2 is a sp3 hybridized structure with 2 lone pairs . So resultant shape is V-Type . We know that in sp3 structure bond angle is 109.47 but high electro-negative oxygen atom, attracts Cl-O bonded electrons toward oxygen creating repulsions . So angle is slightly increases to 110.9.

    How do you know which molecule has the largest bond angle? ›

    The molecules having sp hybridization will have largest bond angle because in sp hybridization bond angle is 180° and examples are CO2 , BeCl2 , BeH2 etc . Any molecule having “sp” hybridization or linear shape. So the largest possible angle in any molecule is 180°.

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